Journal
ORGANIC LETTERS
Volume 21, Issue 11, Pages 4143-4147Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01333
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Funding
- NSFC [21877020]
- Guangdong Natural Science Funds for Distinguished Young Scholar [2017A030306031]
- Natural Science Foundation of Guangdong Province [2018A030313274]
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The efficient couplings of diverse N-arylureas and methyleneoxetanones have been realized via Rh(III)-catalyzed and solvent-controlled chemoselective C-H functionalization, which involved the tunable beta-H elimination and beta-O elimination processes, thereby giving divergent access to quinolin-2(1H)-ones and ortho-allylated N-arylureas with broad substrate compatibility and good functional group tolerance. the divergent synthetic utilities of the transformations have also been exemplified by subsequently tandem C-H allylation, unsymmetrical C-H functionalization, alternative reaction mode, as well as removal of the carbamoyl group.
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