Journal
ORGANIC LETTERS
Volume 21, Issue 10, Pages 3490-3495Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00626
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Funding
- SERB (DST, New Delhi) through ECRA [ECR/2016/000262]
- IITG
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We demonstrate here that the strained and bulky protonated 2,4,6-tri-tert-butylpyridine salts serve as efficient catalysts for highly stereoselective glycosylations of various glycals. Moreover, the mechanism of action involves an interesting single hydrogen bond mediated protonation of glycals and not via the generally conceived Bronsted acid pathway. The counteranions also play a role in the outcome of the reaction.
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