Journal
ORGANIC LETTERS
Volume 21, Issue 10, Pages 3471-3475Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00042
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Funding
- National Science Foundation [CHE-1412670]
- Department of Chemistry at the University of New Orleans
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A reliable method for encapsulation of palladium nanoparticles (6-8 nm particles) in halloysite (Pd@Hal) has been developed. The Pd@Hal was found to be a highly efficient room-temperature catalyst for Suzuki- Miyaura cross-coupling reactions that gave high yields of a diverse array of coupling products in 5:2 n-PrOH/H2O within 1 h. The catalytic system was remarkably effective with a broad substrate scope. In addition, the catalyst was easily recovered and recycled without a significant loss of catalytic activity.
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