Journal
ORGANIC LETTERS
Volume 21, Issue 10, Pages 3817-3821Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01260
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Funding
- American Chemical Society [57219DNI4]
- Iowa State University of Science and Technology
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A new class of push-pull dyes based on the reactive isobenzofuran core have been synthesized. The new dyes have a smaller HOMO-LUMO gap than a related class of dyes based on benzofurazan and allow for isolation of structural factors that contribute to environmental sensitivity. Experimental and theoretical evidence implicate different photophysical processes are responsible for a reversal of emissive behavior that is observed between isobenzofuran and benzofurazan analogues.
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