4.8 Article

Direct Access to Alkylideneoxindoles via Axially Enantioselective Knoevenagel Condensation

Journal

ORGANIC LETTERS
Volume 21, Issue 9, Pages 3013-3017

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00505

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Funding

  1. University of Bologna

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The organocatalytic axially enantioselective Knoevenagel condensation between prochiral cyclohexanones and oxindoles is presented. The reaction, promoted by a primary amine, proceeded smoothly and furnished unprecedented examples of novel cyclohexylidene oxindoles displaying axial chirality.

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