4.8 Article

Visible-Light-Mediated Sulfonylimination of Tertiary Amines with Sulfonylazides Involving Csp3-Csp3 Bond Cleavage

Journal

ORGANIC LETTERS
Volume 21, Issue 8, Pages 2804-2807

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00786

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Funding

  1. NKRDPC [2016YFA0602900]
  2. NSFC [21871097]
  3. GPSF [2017B090903003]
  4. GNSF [2018B030308007]

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Visible-light-induced cross-coupling of arylsulfonyl azides with tertiaryamines in the presence of Eosin Y at room temperature has been achieved. This transformation features alkyl C-C bond cleavage and provides a green approach to N-sulfonylamidines under mild conditions.

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