4.2 Article

Alkylthio(4-methylpent-3-en-1-ynyl)carbenes: generation by the photolysis of 5-alkylthioethynyl-3,3-dimethyl-3H-pyrazoles and reactions with alkenes

Journal

MENDELEEV COMMUNICATIONS
Volume 29, Issue 2, Pages 140-142

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.mencom.2019.03.006

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Funding

  1. Russian Foundation for Basic Research [18-03-01037 A]

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New singlet alkylthio(4-methylpent-3-en-1-ynyl)carbenes were generated by photolysis of corresponding 5-alkylthioethynyl-3,3-dimethyl-3H-pyrazoles and subsequently trapped by alkenes giving rise to 1-alkynyl-1-(alkylthio)cyclopropanes in yields up to 60%.

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