4.5 Article

Mechanical properties of CF-reinforced PLA parts manufactured by fused deposition modeling

Journal

JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS
Volume 34, Issue 5, Pages 581-595

Publisher

SAGE PUBLICATIONS LTD
DOI: 10.1177/0892705719847244

Keywords

Thermoplastics; fused deposition modeling; mechanical properties; crystallinity; annealing

Funding

  1. Euro-Mediterranean University of Fes
  2. Hassan II Academy of Sciences and Technologies (Morocco)
  3. Safran Composites (France)

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The study focused on the influence of nozzle temperature and infill line orientations on parts made with short carbon fiber-reinforced polylactic acid, as well as the effects of annealing on crystallinity and mechanical properties. Results showed that high nozzle temperature and specific infill orientations can improve tensile properties, while annealing can increase crystallinity and Young's modulus.
Many parameters of fused deposition modeling (FDM) influence the resulting mechanical properties. This can become a key factor if those parts are intended for commercial applications. This study focuses on the influence of nozzle temperature and infill line orientations for parts made with short carbon fiber (CF)-reinforced polylactic acid (PLA). Tests bars made of PLA and PLA-CF composite were produced under carefully selected conditions. As expected, PLA-CF yields higher tensile properties compared to PLA, owing to the strengthening effect of high modulus CFs. Maximum tensile properties are attained for a nozzle temperature of 230 degrees C, for both PLA and PLA-CF. This temperature was thus selected for probing the effects of infill orientations in test bars. Among the multiple orientations tested, the combination [0 degrees, 15 degrees, -15 degrees] relative to the long axis of the test bar yields the highest levels of tensile properties for both PLA and PLA-CF over the all-purpose [45 degrees, 135 degrees] orientation. Annealing can also affect crystallinity and mechanical properties of manufactured parts. Through differential scanning calorimetric analyses, the degree of crystallinity was assessed for samples annealed under various conditions. Results show that annealing increases crystallinity in PLA and PLA-CF samples, with a lower cooling rate yielding higher values. The Young's modulus exhibits the same behavior for annealed and as printed parts, with a lower cooling rate yielding higher modulus values. This is attributed to a relaxation of the material structure as well as to the orientation of polymer chains toward the CFs.

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