4.5 Article

Extrusion processing of a high fibre loading of agrowaste in recycled polyolefin biocomposite

Journal

JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS
Volume 34, Issue 1, Pages 40-54

Publisher

SAGE PUBLICATIONS LTD
DOI: 10.1177/0892705719838015

Keywords

Blending; compatibilizer; coupling; modification; mechanical; morphologies; FTIR

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The study demonstrated that interfacial modification using alkalization, compatibilization, and coupling agent improved the mechanical performance and morphological stability of biocomposites. Scanning electron microscope images revealed enhanced interaction between matrix and filler after modification.
A high loading rice husk fibre (RHF) incorporated polyolefin blend of recycled polyethylene high-density/poly(ethylene terephthalate) (rPEHD/rPET) biocomposite was produced through extrusion and hot/cold press process. Interfacial modification of biocomposites was conducted through alkalization (sodium hydroxide solution) of fibres, compatibilization (using E-GMA) and/or coupling agent (MA-g-PE) to improve the interaction between components and the homogeneity of materials blending. Alkalization of fibres had improved the impact strength of biocomposites. The compatibilization and coupling effects on immiscible rPEHD/rPET blend and recycled polymer/RH filler, respectively, had led to an enhancement of mechanical performance and morphological stability. Scanning electron microscope micrograph revealed the improved matrix-matrix and filler-matrix interaction through interfacial modification. This investigation had shown that RHF mixed well with rPEHD/rPET/RHF to produce eco-friendly biocomposite products.

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