Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 141, Issue 16, Pages 6468-6472Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b01241
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Funding
- U.S. Department of Energy Office of Basic Energy Sciences [DE-FG02-01ER15186]
- King Abdullah University of Science and Technology (KAUST) [OSR-2017-CRG6-3503.01]
- R. A. Welch Foundation [F-1018]
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We report an expanded Texas-sized molecular box (AzoTxSB) that incorporates photo responsive azobenzene bridging subunits and anion recognition motifs. The shape of this box can be switched through light induced E <-> Z photoisomerization of the constituent azobenzenes. This allows various anionic substrates to be bound and released by using different forms of the box. Control can also be achieved using other environmental stimuli, such as pH and anion competition.
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