Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 10, Pages 6199-6206Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b00416
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Funding
- NSFC [21633013, 21101109, 21602228]
- NSF of Jiangsu Province [BK20160394]
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An efficient GaCl3-catalyzed direct cyanation of indoles and pyrroles using bench-stable electrophilic cyanating agent N-cyanosuccinimide was achieved and afforded 3-cyanoindoles and 2-cyanopyrroles in good yields and excellent regioselectivities. Notably, this protocol exhibited high reactivity for unprotected indoles and was applicable to a broad range of indole and pyrrole substrates.
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