Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 12, Pages 7894-7900Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b00685
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Funding
- National Natural Science Foundation of China [21272177]
- Natural Science Foundation of Guangxi Province [2018GXNSFDA281011]
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Copper-catalyzed aerobic oxidative sulfuration and annulation of propargylamines with elemental sulfur is described. The tandem reaction involves C-N bond cleavage and the formation of multiple C-S bonds, affording 1,2-dithiole-3-thiones in good to excellent yields with good functional group tolerance.
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