4.5 Article

Highly responsive and selective formaldehyde sensor based on La3+-doped barium stannate microtubes prepared by electrospinning

Journal

JOURNAL OF MATERIALS RESEARCH
Volume 34, Issue 12, Pages 2067-2077

Publisher

CAMBRIDGE UNIV PRESS
DOI: 10.1557/jmr.2019.95

Keywords

sensor; dopant; electrodeposition

Funding

  1. NSFC [61671019]

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La3+-doped BaSnO3 microtubes (La3+-BaSnO3) have been synthesized by electrospinning method, and the influence of La3+ content on the sensing properties of BaSnO3 for detection of formaldehyde vapor has been investigated. The as-prepared materials have been characterized using XRD, SEM, DSC, XPS, and UV-Vis. The La3+-BaSnO3 sample doped with 4 wt% La exhibited a response as high as 220 to formaldehyde vapor (1000 ppm concentration) along with a very low detection limit of 0.1 ppm at 270 degrees C, whereas at 140 degrees C, it exhibited a response of 80 and detection limit of 1 ppm. In addition, the sensor showed excellent selectivity of 57 to formaldehyde at 140 degrees C when compared with other vapors. Further, the sensor also showed good repeatability and stability over a long period of time suggesting its strong potential as a commercial formaldehyde sensor.

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