4.7 Article

Electrochemical enantioselective recognition penicillamine isomers based on chiral C-dots/MOF hybrid arrays

Journal

JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 846, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2019.05.033

Keywords

Chiral C-dots; Metal-organic framework; Self-supported electrode; Chiral electrochemical recognition; PA enantiomers

Funding

  1. National Key Scientific Instrument and Equipment Development Projects of China [21627809]
  2. National Natural Science Foundation of China [21605058, 21575050, 21375047]

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We firstly report a simple and effective chiral electrochemical sensing platform based on chiral C-dots inserted into a metal-organic framework, which was directly grown on the surface of Cu foil (denoted as C-dots@MOF/CuF). The C-dots@MOF/CuF electrode shows excellent selectivity, prominent sensitivity and quantitative analysis towards PA enantiomers. To our knowledge, it presents the first example of a chiral C-dots hybrid for chiral recognition.

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