Journal
JOURNAL OF CATALYSIS
Volume 372, Issue -, Pages 272-276Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2019.03.001
Keywords
Iron catalyst; Carbonylation; Cyclobutanone oximes; Ketone; Domino reaction; Coupling
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Herein we present an efficient carbonylative protocol for the introduction of an alkyl-acyl group into heteroarenes from cyclobutanone oximes. In the presence of Fe(OTf)(2) catalyst, proceeds via intermolecular alkyl-acylation of different heteroarenes. A broad range of alkyl heteroaryl ketones are synthesized with excellent functional group tolerance with good chemoselectivity. (C) 2019 Elsevier Inc. All rights reserved.
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