Journal
JOURNAL OF CATALYSIS
Volume 373, Issue -, Pages 139-146Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2019.03.041
Keywords
Pt(II) complexes; Supramolecular chemistry; Catalysis; Hydrosilylation; Functionalized olefins
Categories
Funding
- National Science Centre [2018/30/E/ST5/00032, UM0-2016/21/N/ST5/00851]
- European Union through the European Social Fund under the Operational Program Knowledge Education Development
- [POWR.03.02.00-00-1023/17]
Ask authors/readers for more resources
Two new air- and water-stable Pt(II) metallosupramolecular complexes based on ambidentate ligands have been designed, synthesized and fully characterized. The structure of complexes has been determined by various analytical techniques including NMR spectroscopy and TOF-MS. Additionally, the single crystal structure of 2 was determined by X-ray diffraction. The catalytic activity of these complexes in hydrosilylation has been investigated, establishing that both have similar high activity and selectivity within a broad scope of structurally distinct olefins and hydrosilanes. (C) 2019 Elsevier Inc. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
