4.6 Article

Ultralight nanocomposite aerogels with interpenetrating network structure of bacterial cellulose for oil absorption

Journal

JOURNAL OF APPLIED POLYMER SCIENCE
Volume 136, Issue 39, Pages -

Publisher

WILEY
DOI: 10.1002/app.48000

Keywords

adsorption; cellulose and other wood products; fibers; oil and gas

Funding

  1. national first-class discipline program of Light Industry Technology and Engineering [LITE2018-21]
  2. National Natural Science Foundation of China [51641303]
  3. Priority Academic Program Development of Jiangsu Higher Education Institutions
  4. Industry-Academia-Research Joint Innovation Fund of Jiangsu Province [BY2016022-03]

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Towards the development of novel platforms for oil absorption and environmental remediation, bacterial cellulose aerogels (BCA), a lightweight and highly porous material, were modified with carbon nanotubes (CNT) and carboxylic carbon nanotubes (CCNT), respectively, at both 5 and 10 wt % loading. The resulting nanocomposite materials, termed BCA/CNT and BCA/CCNT, demonstrated improved oil absorption property when tested against liquid paraffin (glycerol), vacuum oil, plant oil, and propanetriol. After a single immersion lasting about 4-119 seconds, BCA/CNT 10% absorbed an average of 120.23 (standard deviation: 1.145) g center dot g(-1) of propanetriol. While BCA is known to be fragile, but no destruction was observed before and after oil absorption. The difference between CNT and CCNT is carboxylation, which could reduce hydrophilicity. The samples were characterized by scanning electron microscope (SEM), Fourier transform infrared spectrum (FTIR), Brunauer-Emmett-Teller (BET) analysis, contact angle test, and mechanical test. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48000.

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