Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 103, Issue -, Pages 72-74Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2019.03.014
Keywords
Halometalate; Halide complexes; Bismuth; Crystal structure; Hirshfeld surface analysis
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Funding
- Russian Science Foundation [18-73-10040]
- Russian Federation
- Russian Science Foundation [18-73-10040] Funding Source: Russian Science Foundation
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Tetranuclear bromobismuthate anion [Bi4Br18](6-) of a brand-new structural type was found in a complex ((3,5-MePy)C-2)(3)[Bi4Br18] (1) which was obtained by reaction of 1,1'-(ethane-1,2-diyl)bis(3,5-dimethylpyridin-1-ium) dibromide ((3,5-MePy)C2Br2) with solution of Bi2O3 in HBr. Hirshfeld surface analysis was performed for the crystal structure of 1, revealing the nature of interactions in solid state.
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