4.7 Article

One-step synthesis of confined ion Agx-Cu-BTC for selective catalytic reduction of NO with CO

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 102, Issue -, Pages 130-133

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2019.02.027

Keywords

Porous materials; Crystal growth; One-step synthesis; Microstructure; Cu-BTC

Funding

  1. [738010004]
  2. [2017GK4010]

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Ag2O dispersed in Bi-metal organic framework Ag-x-Cu-BTC were firstly prepared by preassembled method (PAM). These catalysts have regular octahedral shape with high specific surface area. In addition, mixed-node Ag-x-Cu-BTC show better performance for CO-SCR with the addition of Ag cations that enhance CO-SCR activity under the same condition at a lower temperature (< 240 degrees C). The addition of Ag cations into metallic framework results in promoting the catalysts activity and increasing reaction activated sites, suggesting that metal organic frameworks should be a promising material for SCR of denitrification. It also promotes a new method for acquiring metal oxides/metal organic frameworks.

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