Journal
ELECTROCHIMICA ACTA
Volume 301, Issue -, Pages 294-303Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2019.01.173
Keywords
Hierarchical porous sphere; Binary transition metal oxides; MnCo2O4; Asymmetric supercapacitor
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Funding
- National Key Research and Development Plan of China [2016YFC0305004]
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A binary transition metal oxides MnCo2O4 with hierarchical porous sphere structure (MnCo2O4 PSs) electrode material for supercapacitor was prepared by a moderate methanol solvothermal and calcination method. The MnCo2O4 PSs presents a large specific surface area (213.2 m(2) g(-1)). Hierarchical porous sphere is beneficial for forming conductive networks and furnishing more electrochemically active sites. Amazingly, the MnCo2O4 PSs exhibits brilliant electrochemical properties that a relatively high specific capacitance of 1044 F g(-1) and remarkable cycling stability (133.3% retention after 10000 cycles) are owned. A mimetic asymmetric supercapacitor (ASC) was constructed by the MnCo2O4 PSs and the starch-derived carbon foam material (SCF) as positive and negative electrode, respectively. The MnCo2O4 PSs//SCF ASC shows excellent specific energy (42.27 Wh kg(-1)) at the specific power of 400 W kg(-1) under the optimal output potential difference of 1.6 V and long-term cycling stability. Herein, the MnCo2O4 PSs electrode material prepared in this work is a distinguished candidate material for supercapacitor. (C) 2019 Elsevier Ltd. All rights reserved.
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