Journal
ELECTROCHIMICA ACTA
Volume 302, Issue -, Pages 310-315Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2019.02.041
Keywords
Oxidative coupling; Anode; Rearrangement; Polycyclic arenes; Electrolysis
Categories
Funding
- German Research Foundation DFG, Center for INnovative and Emerging Materials [WA 1276/15-1]
- Carl-Zeiss-Stiftung
- Graduate School of Excellence MAterial Science IN MainZ (MAINZ)
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Electro-organic conversions at an active molybdenum anode enable the formation of fused arenes. High chemoselectivity was achieved under anodic conditions, and a reagent-induced selectivity was observed by comparison with results of MoCl5-mediated reactions. Polycyclic arenes like phenanthrenes, triphenylenes, chrysenes, or helicenes were selectively obtained in yields up to 87% and in some cases unusual rearrangements were crucial for the product formation. (C) 2019 Elsevier Ltd. All rights reserved.
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