Journal
COORDINATION CHEMISTRY REVIEWS
Volume 386, Issue -, Pages 32-49Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2019.01.017
Keywords
Reticular chemistry; Zr-MOFs; edge-transitive nets; porous materials; post-synthetic modification; gas storage and separation
Categories
Funding
- Inorganometallic Catalyst Design Center, an EFRC - DOE, Office of Science, Basic Energy Sciences [DE-SC0012702]
- Defense Threat Reduction Agency [HDTRA1-18-1-0003]
- ARO-STIR [W911SR18C0031]
- U.S. Department of Energy (DOE) Office of Science, Basic Energy Sciences Program [DE-FG02-08ER155967]
- U.S. Department of Energy, National Nuclear Security Administration [DE-NA0003763]
- Northwestern University
- U.S. Department of Energy (DOE), Office of Science, Office of Workforce Development for Teachers and Scientists, Office of Science Graduate Student Research (SCGSR) program
- ORAU [DE-SC0014664]
- Ryan Fellowship program of the Northwestern University International Institute of Nanotechnology
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In the past two decades, reticular chemistry has developed into a powerful tool for the design and synthesis of porous, crystalline framework materials. The discovery of the first hexanuclear, zirconium cluster-based MOF (i.e. UiO-66; fcu net) led to a vast library of functional Zr-MOFs with various properties. The versatile connectivity of zirconium hexanuclear clusters and the adaptable tunability of organic ligands have resulted in the rational synthesis of a large set of Zr-MOFs based on edge-transitive nets; these nets commonly exists in crystalline network structures as suggested by reticular chemistry. In this review, we summarize recent advances in the synthesis of zirconium cluster-based MOFs in the light of reticular chemistry design principles. Isoreticular tuning of MOF parent structures and post-synthetic modification of Zr-MOFs for targeted applications are also deliberated. (C) 2019 Elsevier B.V. All rights reserved.
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