Graphene modified anatase/titanate nanosheets with enhanced photocatalytic activity for efficient degradation of sulfamethazine under simulated solar light

Graphene modified anatase/titanate nanosheets (G/A/TNS) synthesized through hydrothermal treatment were used for solar-light-driven photocatalytic degradation of a typical pharmaceutically active compound, sulfamethazine (SMT). The optimal material was synthesized with 0.5 wt% of graphene loading (G/A/TNS-0.5), which could efficiently degrade 96.1% of SMT at 4 h. G/A/TNS-0.5 showed enhanced photocatalytic activity compared with the neat anatase and unmodified anatase/titanate nanosheets (A/TNS). UV-vis diffuse reflection spectra indicated that G/A/TNS-0.5 had a lower energy band gap (E-g) of 2.8 eV than A/TNS (3.1 eV). The grafted graphene acted as an electron transfer mediator after photoexcitation, resulting in inhibition on rapid recombination of electron-hole pairs. More importantly, architecture of graphene and titanate nanosheets both with two-dimensional structures greatly facilitated the photoexcited electron transfer. center dot OH and O-1(2) were the primary reactive oxygen species (ROS) to SMT degradation. Fukui index (f(-)) derived from density functional theory (DFT) calculation predicted the active sites on SMT molecule, and then SMT degradation pathway was proposed by means of intermediates identification and theoretical calculation. Furthermore, G/A/TNS-0.5 could be well reused and 90.5% of SMT was also degraded after five runs. The developed new photocatalysts show great potential for degradation of emerging organic contaminants through photocatalysis under solar light. (C) 2019 Elsevier Ltd. All rights reserved.