Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 25, Issue 37, Pages 8719-8724Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201902122
Keywords
benzannulation; iridium; doping; phosphorescence; polycyclic aromatic hydrocarbons (PAHs)
Categories
Funding
- Robert A. Welch Foundation [F-0038, F-1885, Y-0026]
- NSF [CHE-1565688]
- Japan Student Services Organization (JASSO)
- University Graduate Continuing Fellowship
- University of Texas at Austin Provost Fellowship
Ask authors/readers for more resources
Cyclometalation of a triple helical N-doped phenylene cage prepared by ruthenium(0)-catalyzed diol-diene benzannulation delivers a chiral, conformationally constrained Ir(ppy)(3) analogue. Like the parent complex, fac-Ir(ppy)(3), the iridium-containing PAH-cage is phosphorescent, but displays enhanced resistance to oxygen quenching.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available