Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 25, Issue 22, Pages 5719-5732Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201806304
Keywords
ambipolar; charge transfer; coordination chemistry; liquid crystals; platinum
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Funding
- CNRS
- Rennes Metropole
- University of Rennes 1
- GENCI [2018-A0040805032]
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Platinum diimine dithiolene complexes bearing mesogenic groups on one or both ligands have been prepared through an original ligand metathesis reaction to introduce the dithiolene ligand. The neutral diimine ligands, the intermediate platinum dichloride diimine complexes, and the target compounds were characterized by a combination of electronic (electrochemistry, absorption and emission spectroscopy, DFT calculations) and structural (SAXS, DSC) tools. Several novel liquid crystalline platinum diimine-dithiolene were identified over a large temperature range, and the systems were endowed with ambipolar properties, associated with the high reversibility of both oxidation and reduction processes.
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