Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 25, Issue 15, Pages 3761-3765Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201805678
Keywords
clusters; insertion; organosilicon compounds; palladium; template synthesis
Categories
Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [16H04120]
- Samco Science and Technology Foundation
- Institute of Industrial Science, The University of Tokyo
- Grants-in-Aid for Scientific Research [16H04120] Funding Source: KAKEN
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The construction of well-defined transition-metal clusters has attracted substantial attention due to their unique chemical and/or physical properties. Metal clusters with 1D or 2D structures are now accessible by template-synthesis methods, in which multiple metal atoms are arranged with the aid of template molecules and their 1D or 2D structures. However, the rational synthesis of 3D clusters remains challenging, mostly due to a lack of appropriate template molecules. Herein, we report the rational synthesis of a 2D butterfly shaped Pd-4 framework (2) and 3D edge-sharing Pd-6 tetrahedra (5) by treatment of easily available organosilicon compounds with Pd(CNtBu)(2). The diphenylsilylene moiety thereby serves as the key component to generate the butterfly structure of the Pd-4 clusters in 2. A dimensionality expansion, induced by two Cl atoms, of two butterfly shaped Pd-4 subunits supported by two diphenylsilylene moieties afforded the edge-sharing tetrahedral architecture of the Pd-6 cluster in 5.
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