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N-Heterocyclic Carbenes in Materials Chemistry

Journal

CHEMICAL REVIEWS
Volume 119, Issue 8, Pages 4986-5056

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.8b00514

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Funding

  1. Natural Sciences and Engineering Research Council of Canada (NSERC)
  2. Canada Foundation of Innovation (CFI)
  3. Japan Society for the Promotion of Science
  4. Queen's University
  5. GreenCentre Canada
  6. Nagoya University

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N-Heterocyclic carbenes (NHCs) have become one of the most widely studied class of ligands in molecular chemistry and have found applications in fields as varied as catalysis, the stabilization of reactive molecular fragments, and biochemistry. More recently, NHCs have found applications in materials chemistry and have allowed for the functionalization of surfaces, polymers, nanoparticles, and discrete, well-defined clusters. In this review, we provide an in-depth look at recent advances in the use of NHCs for the development of functional materials.

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