4.6 Article

A Broader-scope Analysis of the Catalytic Reduction of Nitrophenols and Azo Dyes with Noble Metal Nanoparticles

Journal

CHEMCATCHEM
Volume 11, Issue 11, Pages 2590-2595

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201900260

Keywords

heterogeneous catalysis; noble metal nanoparticles; nitrophenol reduction; aqueous catalysis; green chemistry

Funding

  1. Department of Chemistry, Department of Physics, College of Sciences at the University of Central Florida
  2. FCI at the University of Central Florida
  3. UCF Office of Undergraduate Research
  4. NSF [MRI: XPS: ECCS: 1726636]

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In addition to the broad environmental implications associated with the removal of nitroaromatics from industrial effluent, the catalytic reduction of 4-nitrophenol (4NP) has emerged as a benchmark model for quantifying catalytic activity of metal nanoparticles. Here we present a series of noble metal nanoparticles immobilized on amorphous carbon (Au@C, Ag@C, Pt@C and Pd@C). All materials show competitive catalytic activity over 4NP, amino-substituted nitrophenols (ANPs) and azo dyes. Overall, Pd@C exhibits superior activity that increases further when exposed to recycling protocol. Moreover, testing all materials synthesized over a broader substrate scope with added functionalities reveals inconsistencies in the prognosticating ability of the ubiquitous 4NP model reaction. By incorporating variably substituted ANPs into the substrate scope and averaging performance, the resulting rank of catalyst activity more accurately reflects activity trends when applied to other reducible functionalities, such as -N=N- groups in azo dyes.

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