Journal
CELLULOSE
Volume 26, Issue 7, Pages 4463-4478Publisher
SPRINGER
DOI: 10.1007/s10570-019-02393-1
Keywords
Biocomposite foams; Starch; cellulose composite foams; PLA; Rheology; Thermomechanical properties
Funding
- Ministry of Business, Innovation, and Employment (MBIE) of the Government of New Zealand through the Biopolymer Network Ltd. [BPLY1302]
- New Zealand Ministry of Business, Innovation & Employment (MBIE) [BPLY1302] Funding Source: New Zealand Ministry of Business, Innovation & Employment (MBIE)
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Expanded polystyrene foams are lightweight and cheap, but they have excellent strength and insulation properties. However, their inability to biodegrade in traditional landfill situations makes their disposal problematic. Starch, a polysaccharide, has the potential to replace synthetic thermoplastics for some applications but starch-based foams are hydrophilic, which limits their applications. In this work, polylactide (PLA), a sustainably derived and industrially compostable polymer, was added to starch/cellulose composite foams to enhance their water barrier properties. PLA powder at various weight % was mixed with moistened starch and cellulose mixture, and composite foams were prepared by compression moulding at 220 degrees C. The thermomechanical and viscoelastic properties of the produced foam materials were analysed by thermogravimetric analysis, dynamic mechanical thermal analysis, mechanical testing, and also by the 3-point compressive mechanical quasi-static testing. It was found that the tensile strength of the composite foams increased with an increase in the PLA loading, which increased from 2.50MPa for 0% PLA to 3.27MPa for 9.72% PLA loading. The flexural strength also increased from 345.91kPa for the 0% PLA to 378.53kPa for the composite foam containing 4.86% PLA;beyond which the flexural strength started decreasing with an increase in PLA loading. Similarly, the stiffness of the starch/cellulose composite also increased with an increase in PLA loading up to 4.86%, and further increase in PLA loading decreased the stiffness. The flexural modulus of the composite foams increased from 522MPa for 0% PLA loading to 542.85MPa for the 4.86% PLA loading. The thermal stability of the starch/cellulose composite foams also increased and the water absorbency decreased with the increased PLA loading. [GRAPHICS] .
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