Journal
CATALYSIS TODAY
Volume 346, Issue -, Pages 76-80Publisher
ELSEVIER
DOI: 10.1016/j.cattod.2019.04.048
Keywords
Glycerol; Acetalization; Heteropolyacids; Heterogeneous catalysis; Green processes
Funding
- [PTDC/CTMPOL/114579/2009]
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Dodecamolydbophosphoric acid (HPMo) immobilized on USY zeolite was used as a catalyst for the acetalization of glycerol with pentanal at 70 degrees C. Catalysts were prepared with different amounts of heteropolyacid, and the most active sample was the HPMo2@Y catalyst (1.1 wt.%). The products of glycerol acetalization with pentanal were (2-butyl-1,3-dioxolan-4-yl)methanol, a five-member ring compound, and 2-butyl-1,3-dioxan-5-ol, a six-member ring compound. Good values of selectivity for the five-member ring compound (80-85%) were obtained with all materials. The reaction conditions were optimized using HPMo2@Y as a catalyst. The optimal conditions were determined to be 70 degrees C reaction temperature with 0.3 g catalyst and a 1:2.5M ratio of glycerol to pentanal. The catalytic stability of HPMo2@Y was studied. The acetalization of glycerol with pentanal was performed using the same sample. High catalytic activity for HPMo2@Y was observed.
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