Journal
BIOFUELS BIOPRODUCTS & BIOREFINING-BIOFPR
Volume 13, Issue 4, Pages 1068-1084Publisher
WILEY
DOI: 10.1002/bbb.1999
Keywords
lignin valorization; lignin depolymerization; techno-economic analysis; lignocellulosic biorefinery; pyrolysis; hydrodeoxygenation; hydrothermal upgrading; biobased aromatics
Funding
- Smart Mix Program of the Netherlands, Ministry of Economic Affairs
- Netherlands Ministry of Education, Culture and Science [053.70.381]
- Netherlands Ministry of Economic Affairs
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This paper presents a techno-economic assessment of three novel routes for the production of bio-based aromatics from lignin. It aims to provide insights into their feasibility and hotspots at an early stage of development to guide further research and development and to facilitate commercialization. The lignin conversion routes are: (non-catalytic) lignin pyrolysis, direct hydrodeoxygenation (HDO), and hydrothermal upgrading (HyThUp). The products generated are mixed oxygenated aromatic monomers (MOAMON), light organics, heavy organics, and char. For the technical assessment, conceptual design followed by process modeling in Aspen Plus was based on experimental yields. The models generated indispensable data on material and energy flows. An economic assessment was then conducted by estimating operating and capital costs. Return on investment (ROI), payback period (PBP), and net present value (NPV) were used as key performance indicators. Downstream processing was especially demanding in the HyThUp process due to the presence of a significant flow rate of water in the system, which significantly increased external utility requirements. Due to complex separations, the HyThUp process showed the highest capital cost (35% more than pyrolysis). Operating costs were the highest for the direct HDO process (34% more than pyrolysis) due to the use of hydrogen. Overall, the direct HDO process showed the highest ROI (12%) and the shortest PBP (5 years) due to high yields of valuable heavy organics (32%) and MOAMON (24%). Direct HDO was found to be feasible with a positive NPV based on prices used in the assessment. Among the three processes investigated, the direct HDO process therefore appeared to be the most promising, and consideration should be given to further development and commercialization of this process. (c) 2019 The Authors. Biofuels, Bioproducts, and Biorefining published by Society of Chemical Industry and John Wiley & Sons, Ltd.
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