Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 21, Pages 7013-7019Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201902090
Keywords
charge transfer; chirality; circularly polarized luminescence; organogels; self-assembly
Categories
Funding
- National Natural Science Foundation of China [21802027, 51673050, 91856115]
- Ministry of Science and Technology of the People's Republic of China [2017YFA0206600, 2016YFA0203400]
- Key Research Program of Frontier Sciences, CAS [QYZDJ-SSW-SLH044]
- New Hundred-Talent Program research fund of the Chinese Academy of Sciences
- China Postdoctoral Science Foundation
- Super Computing Center ScGrid/CNGrid of CAS
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Achieving a large dissymmetry factor (g(lum)) is a challenge in the field of circularly polarized luminescence (CPL). A chiral charge-transfer (CT) system consisting of chiral electron donor and achiral electron acceptor shows bright circularly polarized emission with large g(lum) value. The chiral emissive CT complexes could be fabricated through various approaches, such as grinding, crystallization, spin coating, and gelatinization, by simply blending chiral donor and achiral acceptor. The structural synergy originating from pi-pi stacking and strong CT interactions resulted in the long-range ordered self-assembly, enabling the formation of supramolecular gels. Benefiting from the large magnetic dipole transition moment in the CT state, the CPL activity of CT complexes exhibited large circular polarization. Our design strategy of the chiral emissive CT complexes is expected to help the development of new molecular engineering strategies for designing highly efficient CPL-active materials.
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