Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 27, Pages 9244-9247Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201903839
Keywords
frustrated Lewis pairs; magnesiation; pyridazine; TMP bases; zincation
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Funding
- DFG [SFB749]
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Mono- or bidentate boron Lewis acids trigger a regioselective magnesiation or zincation of pyridazine in position C3 (ortho product) or C4 meta product). The regioselectivity of the metalation was rationalized with the help of calculated pK(a) values of both pyridazine and pyridazine/Lewis acid complexes.
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