Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 4, Pages 1408-1428Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201814439
Keywords
ab initio structure; curved aromatic compounds; electrochemistry; fluorination; photophysical properties
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Funding
- the National Natural Science Foundation of China [51725304, 51633006, 51703159, 51733004, and 91433115] Funding Source: Medline
- the Ministry of Science and Technology of the People_x0002_s Republic of China [2017YFA0204503, 2016YFB0401100] Funding Source: Medline
- the Strategic Priority Research Program [XDB12030300] Funding Source: Medline
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An anthology of fluorous corannulene flowers forms the centerpiece of a chemical landscape sketched out by electronic structure theory that now is being filled in experimentally. Flying above is the transformation enabling the newest blossom, sym-pentafluorocoranulene, the crystal packing structure of which forms the empirical bedrock from which the flowers spring forth. For details read the Communication by K. K. Baldridge, J. S. Siegel, and co-workers on page 1460.
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