Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 361, Issue 12, Pages 2981-2991Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201900034
Keywords
Dibenzoacridine; Cycloisomerisation; Bronsted Acid; Pyridine; Cross-Coupling
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Funding
- federal state of Mecklenburg-Vorpommern
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An efficient and convenient method for the synthesis of dibenzo[c,h]acridine derivatives via electrophilic cycloisomerisation mediated by methanesulfonic acid has been developed. This method provides the desired acridines in moderate to very good yields introducing various substituents in positions 2 and 6 as well as on the dibenzo[c,h]acridine scaffold. Photophysical and electrochemical properties have been investigated for selected products by UV/Vis and CV measurements which have been verified by DFT calculations.
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