Journal
ADVANCED MATERIALS
Volume 31, Issue 23, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201900613
Keywords
DFT calculations; multicolor emissions; single-emissive-layer white organic light-emitting diodes; triphenylamine derivatives
Categories
Funding
- Shenzhen Key Laboratory Project [ZDSYS201603311644527]
- Leading Talents of Guangdong province program [2016LJ06N507]
- Shenzhen Basic Research Fund [CYJ20170817110652558]
- National Key Research and Development Program of China [2018YFB0704100]
- National Natural Science Foundation of China [11474365]
- Foundation of NANO X [18JG01]
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White organic light-emitting diode (WOLED) technology has attracted considerable attention because of its potential use as a next-generation solid-state lighting source. However, most of the reported WOLEDs that employ the combination of multi-emissive materials to generate white emission may suffer from color instability, high material cost, and a complex fabrication procedure which can be diminished by the single-emitter-based WOLED. Herein, a color-tunable material, tris(4-(phenylethynyl)phenyl)amine (TPEPA), is reported, whose photoluminescence (PL) spectrum is altered by adjusting the thermal annealing temperature nearly encompassing the entire visible spectra. Density functional theory calculations and transmission electron microscopy results offer mechanistic understanding of the PL redshift resulting from thermally activated rotation of benzene rings and rotation of 4-(phenylethynyl) phenyl)amine connected to the central nitrogen atom that lead to formation of ordered molecular packing which improves the pi-pi stacking degree and increases electronic coupling. Further, by precisely controlling the annealing time and temperature, a white-light OLED is fabricated with the maximum external quantum efficiency of 3.4% with TPEPA as the only emissive molecule. As far as it is known, thus far, this is the best performance achieved for single small organic molecule based WOLED devices.
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