4.8 Article

High-Performance Symmetric Supercapacitor Constructed Using Carbon Cloth Boosted by Engineering Oxygen-Containing Functional Groups

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 11, Issue 19, Pages 18044-18050

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.9b04426

Keywords

carbon cloth; chemical acid etching; oxygen-containing functional groups; symmetric supercapacitor; flexible supercapacitor

Funding

  1. National Natural Science Foundation of China [51732007, 21802086]
  2. Fundamental Research Funds of Shandong University [2018WLJH64]
  3. Beijing National Laboratory for Molecular Sciences Program [BNLMS201802]
  4. Collaborative Innovation Center of Technology and Equipment for Biological Diagnosis and Therapy in Universities of Shandong

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Carbon materials display appealing physical, chemical, and mechanical properties and have been extensively studied as supercapacitor electrodes. The surface engineering further allows us to tune their capability of adsorption/desorption and catalysis. Therefore, a facile and inexpensive chemical-acid-etching approach has been developed to activate the carbon cloth as an electrode for supercapacitor. The capacitance of the acid-etched carbon cloth electrode can approach 5310 mF cm(-2) at a current density of 5 mA cm(-2) with remarkable recycling stability. The all-solid-state symmetric supercapacitor delivered a high energy density of 4.27 mWh cm(-3) at a power density of 1.32 W cm(-3). Furthermore, this symmetric supercapacitor exhibited outstanding mechanical flexibility, and the capacity remained nearly unchanged after 1000 bending cycles.

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