4.6 Editorial Material

Absence of Oxidized Phases in Cu under CO Reduction Conditions

Journal

ACS ENERGY LETTERS
Volume 4, Issue 3, Pages 803-804

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsenergylett.9b00172

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Funding

  1. Villum Foundation V-SUSTAIN [9455]
  2. Office of Science of the U.S. Department of Energy (DOE) [DE-SC0004993]
  3. National Science Foundation [ECCS-1542152]
  4. DOE Office of Basic Energy Sciences [DE-AC02-76SF00515]
  5. Danish Ministry for Higher Education and Science

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By live-monitoring Cu and Cu2O Bragg peaks from the surface of a polycrystalline Cu electrode while scanning from open-circuit potential to CO reduction potentials, we show that the near-surface region is fully converted to the metallic phase at approximately +0.3 V vs RHE.

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