Journal
MATERIALS RESEARCH EXPRESS
Volume 6, Issue 6, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/2053-1591/ab0cae
Keywords
ferrites; magnetocaloric effect; theoretical models; spontaneous magnetization; critical exponents
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The magnetocaloric effect (MCE) of Ni0.4Mg0.3Cu0.3Fe2O4 ferrite was analyzed by different theoretical methods such as mean-field, Bean-Rodbell and Landau theories. Results confirm the second order type of the ferromagnetic (FM)-paramagnetic (PM) magnetic phase transition for the sample. The values of magnetic entropy change (-Delta S-M) estimated from each theory agree well with those experimentally determined using Maxwell relations. The spontaneous magnetization values (M-spont(T)) determined from both (-Delta S-M versus M-2) and (H/M versus M-2) data are very close, confirming the validity of the magnetic entropy change to estimate M-spont (T) values. The critical exponents (beta, gamma and delta) obtained for Ni0.4Mg0.3Cu0.3Fe2O4 sample at its Curie temperatures (T-C) are close to those predicted in mean-field model.
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