Journal
ENERGY TECHNOLOGY
Volume 8, Issue 2, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ente.201900180
Keywords
calendaring; discrete element method simulations; intercalation; lithium-ion electrodes; microstructure
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Funding
- Federal Ministry for Economic Affairs and Energy (BMWi)
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Herein, a discrete element method (DEM) approach is proposed to investigate the impact of the calendering process on the electrical and ionic conductivities and on the adhesion strength of Li[Ni-1/3 Mn-1/3 Co-1/3]O-2 (NMC)-based electrodes. For this purpose, key correlations between the microstructure and these electrode-scale properties are established using the outcomes of the simulations and real experiments. In addition, the evolution of the structure and the development of mechanical stress are also studied numerically during electrochemical cycling, offering a closer insight into the intercalation mechanism. Finally, the impact of the initial noncalendered porosity on the electrode mechanical response is examined, showing that higher initial porosities lead to lower final porosities under same calendering loads. Overall, this work demonstrates the potential of DEM simulations in improving the understanding of the microstructure and mechanics of lithium-ion electrodes.
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