4.6 Article

Process Design Characteristics of Syngas (CO/H2) Separation Using Composite Membrane

Journal

SUSTAINABILITY
Volume 11, Issue 3, Pages -

Publisher

MDPI
DOI: 10.3390/su11030703

Keywords

composite membrane; polyamide; membrane module temperature; hydrogen; carbon monoxide; stage cut

Funding

  1. National Strategic Project-Carbon Upcycling of the National Research Foundation of Korea (NRF) - Ministry of Science and ICT (MSIT)
  2. Ministry of Environment (ME)
  3. Ministry of Trade, Industry and Energy (MOTIE) [2017M3D8A2089593]
  4. Waste to Energy Recycling Human Resource Development Project of Korea Ministry of Environment (ME)

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The effectiveness of gas separation membranes and their application is continually growing owing to its simpler separation methods. In addition, their application is increasing for the separation of syngas (CO and H-2) which utilizes cryogenic temperature during separation. Polymers are widely used as membrane material for performing the separation of various gaseous mixtures due to their attractive perm-selective properties and high processability. This study, therefore, aims to investigate the process design characteristics of syngas separation utilizing polyamide composite membrane with polyimide support. Moreover, characteristics of CO/H-2 separation were investigated by varying inlet gas flow rates, stage cut, inlet gas pressures, and membrane module temperature. Beneficial impact in CO and H-2 purity were obtained on increasing the flow rate with no significant effect of increasing membrane module temperature and approximately 97% pure CO was obtained from the third stage of the multi-stage membrane system.

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