Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 7, Issue 6, Pages 5892-5899Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.8b05873
Keywords
Biomass; Platform chemicals; Solid acid catalyst; Levoglucosenone; Aqueous phase conversion; 5-Hydroxymethylfutfural; Levulinic acid
Categories
Funding
- MEXT/JSPS KAKENHI [JP16K06845]
- JSPS Joint Research Project, New Zealand Government
- China Scholarship Council [201606420055]
Ask authors/readers for more resources
Levoglucosenone (LGO) is an emerging bio-renewable platform for the fine and commodity chemical industries. Herein, we report an aqueous phase conversion of LGO to 5-hydroxylmethylfurfural (HMF) and levulinic acid (LA) over solid acid catalyst. Several types of solid acid catalysts such as zeolites, strongly acidic ion-exchange resin, and sulfonated activated carbon were investigated for this reaction. Among the tested catalysts, ZSM-5 and Amberlyst 70 showed the best performances for selectively producing the target products, resulting in the highest total yield of HMF and LA at 72.2% on a molar basis. Factors decreasing the reaction selectivity were identified through the comparison of catalysts and kinetic analysis to the pore morphology, presence of Lewis acid sites, and formation of degradation products directly from LGO or its hydrated product. ZSM-5 and Amberlyst 70, after a single-batch experiment, contained deposits from the degradation products but could be reused with little loss in activity, although calcination was required for ZSM-5. The catalytic system, employing LGO as feedstock and recyclable solid acid catalysts, uses only water as reaction media and thus has the potential to be a clean route for producing the key building blocks HMF and LA.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available