4.8 Article

Surface Coordination of Black Phosphorus for Robust Air and Water Stability

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 16, Pages 5003-5007

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201512038

Keywords

black phosphorus; degradation; oxidation; phosphorenes; stability

Funding

  1. National Natural Science Foundation of China (NSFC) [51372175, 31470044]
  2. Leading Talents of Guangdong Province Program [00201520]
  3. Shenzhen Peacock Program [110811003586331]
  4. Shenzhen Science and Technology Research Funding [JCYJ20140417113430608, JCYJ20150401145529017]
  5. City University of Hong Kong Applied Research Grant (ARG) [9667104]

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A titanium sulfonate ligand is synthesized for surface coordination of black phosphorus (BP). In contrast to serious degradation observed from the bare BP, the BP after surface coordination exhibits excellent stability during dispersion in water and exposure to air for a long period of time, thereby significantly extending the lifetime and spurring broader application of BP.

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