Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 48, Pages 15027-15030Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201608250
Keywords
counterions; metal-organic frameworks; rigid nested metal-organic framework; robust dynamics; thermoresponsive gating effect
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Funding
- 973 Program of China [2014CB845600]
- NNSF of China [21290171, 21421001, 21531005, 21403116]
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We herein report a rigid nested metal-organic framework (MOF) featuring a unique thermoresponsive gating adsorption behavior, which, in contrast to any known flexibility modes for stimuli-responsive MOFs, depends on the thermal motion of the extra-framework counterions. In addition, this MOF also exhibits adsorption selectivity of CO2 over N-2, H-2, and Ar at 273 K, thus enabling a strategic separation and encapsulation of CO2.
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