Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 46, Pages 14371-14375Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201607742
Keywords
cobalt; dehydrogenative coupling; pincer complexes; pyrroles
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Funding
- Israel Science Foundation
- MINERVA foundation
- Planning and Budgeting Committee (PBC)
- Swiss Friends of the Weizmann Institute of Science
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Herein, the first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to selectively form functionalized 1,2,5-substituted pyrroles liberating water and hydrogen gas as the sole by-products is presented. The reaction is catalyzed by pincer complexes of earth-abundant cobalt.
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