Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 44, Pages 13739-13743Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201605802
Keywords
alkynes; cooperative effects; heterogeneous catalysis; metal-organic frameworks; porphyrinoids
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Funding
- NSF [CHE-1464941]
- Divisions of Chemistry (CHE) and Materials Research (DMR), National Science Foundation [NSF/CHE-1346572]
- U.S. Department of Energy (DOE) Office of Science [DE-AC02-06CH11357]
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A series of porous twofold interpenetrated InCoIII(porphyrin) metal-organic frameworks (MOFs) were constructed by in situ metalation of porphyrin bridging ligands and used as efficient cooperative catalysts for the hydration of terminal alkynes. The twofold interpenetrating structure brings adjacent Co-III(porphyrins) in the two networks parallel to each other with a distance of about 8.8 c, an ideal distance for the simultaneous activation of both substrates in alkyne hydration reactions. As a result, the In-Co-III(porphyrin) MOFs exhibit much higher (up to 38 times) catalytic activity than either homogeneous catalysts or MOF controls with isolated CoIII(porphyrin) centers, thus highlighting the potential application of MOFs in cooperative catalysis.
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