4.8 Article

A Unique Blend of 2-Fluorenyl-2-anthracene and 2-Anthryl-2-anthracence Showing White Emission and High Charge Mobility

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 3, Pages 722-727

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201608131

Keywords

molecular electronics; organic light-emitting diodes; organic optoelectronics; organic thin-film transistors; semiconductors

Funding

  1. NSFC [51373075, 61136003]
  2. National Research Foundation for the Doctoral Program [20133221110004]
  3. National Basic Research Program of China (973 Program) [2015CB856505, 2015CB932200]
  4. Natural Science Foundation of Jiangsu Province [BM2012010]
  5. Synergetic Innovation Center for Organic Electronics and Information Displays, Shenzhen Key Laboratory of Shenzhen Science and Technology Plan [ZDSYS20140509094114164]
  6. Provincial Science and Technology Project of Guangdong Province [2015B090914002, 2014B090914003]
  7. Guangdong Talents Project, Guangdong Academician Workstation [2013B090400016]
  8. Shenzhen Peacock Program [KQTD2014062714543296]

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White-light-emitting materials with high mobility are necessary for organic white-light-emitting transistors, which can be used for self-driven OLED displays or OLED lighting. In this study, we combined two materials with similar structures-2-fluorenyl-2-anthracene (FlAnt) with blue emission and 2-anthryl-2-anthracence (2A) with greenish-yellow emission-to fabricate OLED devices, which showed unusual solid-state white-light emission with the CIE coordinates (0.33, 0.34) at 10 V. The similar crystal structures ensured that the OTFTs based on mixed FlAnt and 2A showed high mobility of 1.56 cm(2)V(-1)s(-1). This simple method provides new insight into the design of high-performance white-emitting transistor materials and structures.

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