Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 15, Pages 4759-4762Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201512027
Keywords
alkaloids; C-H activation; copper; photocatalysis; total synthesis
Categories
Funding
- European Research Council under the European Community [307535]
- Chinese Scholarship Program
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Room-temperature azole C-H arylations were accomplished with inexpensive copper(I) compounds by means of photoinduced catalysis. The expedient copper catalysis set the stage for site-selective C-H arylations of non-aromatic oxazolines under mild reaction conditions, and provides step-economical access to the alkaloid natural products balsoxin and texamine.
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