Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 7, Pages 2545-2549Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201510394
Keywords
catalysis; electrochemistry; kinetics; soft nanoparticles; turnover numbers
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Funding
- European Research Council under the European Union [320403]
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We report the electrocatalytic dehalogenation of trichloroethylene (TCE) by single soft nanoparticles in the form of Vitamin B-12-containing droplets. We quantify the turnover number of the catalytic reaction at the single soft nanoparticle level. The kinetic data shows that the binding of TCE with the electro-reduced vitamin in the CoI oxidation state is chemically reversible.
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