Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 36, Pages 10806-10810Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201604847
Keywords
copper; homogeneous catalysis; oxidation; reaction mechanisms
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Funding
- Canada Research Chair Foundation
- Canadian Foundation for Innovation
- FRQNT Centre in Green Chemistry and Catalysis
- Natural Science and Engineering Research Council of Canada
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The first example of homogeneous copper-catalyzed aerobic oxidation of aldehydes is reported. This method utilizes atmospheric oxygen as the sole oxidant, proceeds under extremely mild aqueous conditions, and covers a wide range of various functionalized aldehydes. Chromatography is generally not necessary for product purification.
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